AUGUSTINE, CYRIL (2015) HETERONUCLEAR DIPOLAR DECOUPLING IN THE NMR STUDIES OF MOLECULES IN SOLID AND LIQUID-CRYSTALLINE STATES USING A PHASE-WIGGLED SWF-TPPM SEQUENCE. Journal of Basic and Applied Research International, 12 (2). pp. 107-114.
Full text not available from this repository.Abstract
The phase-wiggled two-pulse phase modulation or PW-TPPM, a recently formulated scheme functions effectively for heteronuclear dipolar decoupling in nuclear magnetic resonance of static solid samples [R. Fu, Chem. Phys. Lett. 483, 147, 2009]. In PW-TPPM, the two pulses within each TPPM element have different alternating phase angles and thus these elements become phase-wiggled. In this communication, a modified PW-TPPM scheme is presented, generated by varying pulse durations of the parent PW-TPPM in a way similar to SWf-TPPM (Swept-frequency two-pulse phase modulation) decoupling sequence. The rationale was to find the impact of the tangential variations in pulse durations on the efficiency of PW-TPPM decoupling scheme. The performance of the newly formed sequence, termed as PWSWf-TPPM, is studied in liquid crystals and rotating solids.
Item Type: | Article |
---|---|
Subjects: | Opene Prints > Multidisciplinary |
Depositing User: | Managing Editor |
Date Deposited: | 09 Dec 2023 12:07 |
Last Modified: | 09 Dec 2023 12:07 |
URI: | http://geographical.go2journals.com/id/eprint/3295 |