HETERONUCLEAR DIPOLAR DECOUPLING IN THE NMR STUDIES OF MOLECULES IN SOLID AND LIQUID-CRYSTALLINE STATES USING A PHASE-WIGGLED SWF-TPPM SEQUENCE

AUGUSTINE, CYRIL (2015) HETERONUCLEAR DIPOLAR DECOUPLING IN THE NMR STUDIES OF MOLECULES IN SOLID AND LIQUID-CRYSTALLINE STATES USING A PHASE-WIGGLED SWF-TPPM SEQUENCE. Journal of Basic and Applied Research International, 12 (2). pp. 107-114.

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Abstract

The phase-wiggled two-pulse phase modulation or PW-TPPM, a recently formulated scheme functions effectively for heteronuclear dipolar decoupling in nuclear magnetic resonance of static solid samples [R. Fu, Chem. Phys. Lett. 483, 147, 2009]. In PW-TPPM, the two pulses within each TPPM element have different alternating phase angles and thus these elements become phase-wiggled. In this communication, a modified PW-TPPM scheme is presented, generated by varying pulse durations of the parent PW-TPPM in a way similar to SWf-TPPM (Swept-frequency two-pulse phase modulation) decoupling sequence. The rationale was to find the impact of the tangential variations in pulse durations on the efficiency of PW-TPPM decoupling scheme. The performance of the newly formed sequence, termed as PWSWf-TPPM, is studied in liquid crystals and rotating solids.

Item Type: Article
Subjects: Opene Prints > Multidisciplinary
Depositing User: Managing Editor
Date Deposited: 09 Dec 2023 12:07
Last Modified: 09 Dec 2023 12:07
URI: http://geographical.go2journals.com/id/eprint/3295

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